Anionic photofragmentation of CO: a selective probe of core-level resonances.

نویسندگان

  • W C Stolte
  • D L Hansen
  • M N Piancastelli
  • I Dominguez Lopez
  • A Rizvi
  • O Hemmers
  • H Wang
  • A S Schlachter
  • M S Lubell
  • D W Lindle
چکیده

Anion-yield spectroscopy using x rays is shown to be a selective probe of molecular core-level processes, providing unique experimental verification of shape resonances. For CO, partial anion and cation yields are presented for photon energies near the C K edge. The O- yield exhibits features above threshold related only to doubly excited states, in contrast to cation yields which also exhibit pronounced structure due to the well-known sigma* shape resonance. Because the shape resonance is completely suppressed for O-, anion spectroscopy thus constitutes a highly selective probe, yielding information unobtainable with absorption or electron spectroscopy.

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عنوان ژورنال:
  • Physical review letters

دوره 86 20  شماره 

صفحات  -

تاریخ انتشار 2001