Anionic photofragmentation of CO: a selective probe of core-level resonances.
نویسندگان
چکیده
Anion-yield spectroscopy using x rays is shown to be a selective probe of molecular core-level processes, providing unique experimental verification of shape resonances. For CO, partial anion and cation yields are presented for photon energies near the C K edge. The O- yield exhibits features above threshold related only to doubly excited states, in contrast to cation yields which also exhibit pronounced structure due to the well-known sigma* shape resonance. Because the shape resonance is completely suppressed for O-, anion spectroscopy thus constitutes a highly selective probe, yielding information unobtainable with absorption or electron spectroscopy.
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ورودعنوان ژورنال:
- Physical review letters
دوره 86 20 شماره
صفحات -
تاریخ انتشار 2001